A novel method for synthesis of layered LiNi1/3Mn1/3Co1/3O2 as cathode material for lithium-ion battery

The layered LiNi1/3Mn1/3Co1/3O2 materials with good crystalline are synthesized by a novel method of hydrothermal method followed by a short calcination process. The crystalline structure and morphology of the synthesized materials are characterized by XRD, SEM. Their electrochemical performances are evaluated by CV, EIS and galvonostatic charge/discharge tests. The material synthesized at 850 degrees C for 6 h shows the highest initial discharge capacity of 187.7 mAh g(-1) at 20 mA g(-1). And the capacity retention of 97.9% is maintained at the end of 40 cycles at 1.0 C. CV test reveals almost no shift of anodic and cathodic peaks after first cycle, which indicates good reversible deintercalation and intercalation of Li+ ions. (C) 2009 Elsevier B.V. All rights reserved.