Co-SiO2 nanosphere-catalyzed hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage

Cobalt clusters-silica nanospheres (15-30 nm) were synthesized using a Co(NH3)(6)Cl-3 template method in a polyoxyethylene-nonylphenyl ether/cyclohexane reversed micelle system followed by in situ reduction in aqueous NaBH4/NH3BH3 solutions. The cobalt clusters are located either inside or on the outer surface of the silica nanospheres as shown by the transmission electron microscope (TEM)/energy dispersive X-ray (EDX) and X-ray photoelectron spectroscopy (XPS) measurements. The cobalt-silica nanospheres have a high catalytic activity for the hydrolysis of ammonia borane that generates a stoichiometric amount of hydrogen, and can be efficiently cycled and reused 10 times without any significant loss of the catalytic activity. (C) 2010 Elsevier B.V. All rights reserved.