Journal
JOURNAL OF POWER SOURCES
Volume 195, Issue 4, Pages 1195-1201Publisher
ELSEVIER
DOI: 10.1016/j.jpowsour.2009.08.091
Keywords
Primary lithium batteries; ICD; Cathode; SVO; Ag2V4O11; In situ XRD measurements
Funding
- Office of Naval Research [N00014-07-1-0620]
- Conseil Regional de Picardie (France)
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We investigated the effect of inserting lithium into Ag2V4O11 (epsilon-SVO) on the structure, electronic properties and redox committed by combining in situ XRD measurements, ESR spectroscopy and 4 probes DC conductivity coupled with thermopower measurements. The electrochemical discharge occurs in three consecutive steps above 2 V (vs. Li+/Li). The first one, between 0 < x
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