Journal
JOURNAL OF POWER SOURCES
Volume 189, Issue 1, Pages 66-71Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2008.11.048
Keywords
Solid-electrolyte interfacial layer; ac impedance; Cycling performance; Lithium polymer battery
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The formation of passivating surface films on the electrodes of a lithium-ion polymer battery was investigated at various cycling state using ac impedance spectroscopy and scanning electron microscopy (SEM). A sealed commercial cell (Sony Co.) with a nominal capacity of 840 mAh was used for the experiment. An equivalent circuit used to model the impedance spectra show that, with continuous cycling there is a relatively large increase in the interfacial impedance and charge transfer resistances after a few hundred charge-discharge cycles. It was observed that the cell capacity decrease with increase cell impedance. SEM analysis on the electrodes shows that during continuous charge-discharge cycling, the deposition of sub-micro-size particles and dissolution of surface films on the graphite surface. This observation is consistent with increase in cell impedance as a function of charge/discharge cycling. (C) 2008 Elsevier B.V. All rights reserved.
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