Journal
JOURNAL OF POWER SOURCES
Volume 184, Issue 2, Pages 633-636Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.jpowsour.2008.04.066
Keywords
LiFePO4; Hydrothermal; Complexing-agent; XPS; Mossbauer spectra
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Spherical-like LiFePO4 was synthesized by hydrothermal synthesis method using Phenanthroline as a complexing-agent to avoid the Fe(II) ions from oxidation and control the growth of the crystal. Structural, electron valence state, morphology and particle size were investigated by X-ray diffraction (XRD), X-ray photoelectron spectra (XPS). Mossbauer spectra, scanning electron microscopy (SEM) and laser particle sizer. Charge-discharge cycling performances were used to characterize its electrochemical properties. The sample possesses uniformly distributed spherical-like particles with an average size of 0.5-1 mu m. Test shows that the reversible capacity of spherical-like LiFePO4 is about 140 mAh g(-1) at 0.1 C. The capacity fading is neglectable. (C) 2008 Published by Elsevier B.V.
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