4.1 Article

Carbon nanotubes and metalloporphyrins and metallophthalocyanines-based materials for electroanalysis

Journal

JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
Volume 16, Issue 7-8, Pages 713-740

Publisher

WORLD SCI PUBL CO INC
DOI: 10.1142/S1088424612300054

Keywords

metallophthalocyanines; metalloporphyrins; carbon nanotubes; SWCNT; MWCNT; electroanalysis; electrocatalysis

Funding

  1. CNRS-CONICYT (PICS France/Chile) [5738]
  2. Bilateral projet CNRS-CONACYT (France/Mexico)
  3. Fondecyt Project [1100773]
  4. Nucleo Milenio de Ingenieria Molecular of Chile [P07006]
  5. University of Guanajuato, Mexico [000153/11]
  6. Conicyt

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We discuss here the state of the art on hybrid materials made from single (SWCNT) or multi (MWCNT) walled carbon nanotubes and MN4 complexes such as metalloporphyrins and metallophthalocyanines. The hybrid materials have been characterized by several methods such as cyclic voltammetry (CV), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and scanning electrochemical microscropy (SECM). The materials are employed for electrocatalysis of reactions such as oxygen and hydrogen peroxide reduction, nitric oxide oxidation, oxidation of thiols and other pollutants.

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