Journal
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
Volume 15, Issue 2, Pages 106-110Publisher
WORLD SCI PUBL CO INC
DOI: 10.1142/S1088424611003045
Keywords
gold; corrole; octabromocorrole
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Funding
- Research Council of Norway
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Although a variety of conditions proved unsuccessful for gold insertion into beta-unsubstituted meso-triarylcorroles, refluxing free-base beta-octabromo-meso-triarylcorrole ligands, H-3[Br8T(p-X-P)C] (X = MeO, n-Bu, CH3, H, and CF3), with chloroauric acid in dichloromethane containing a small amount of triethylamine for 30 min led to 54-65% yields of the corresponding gold complexes.
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