Journal
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
Volume 15, Issue 9-10, Pages 883-889Publisher
WORLD SCIENTIFIC PUBL CO PTE LTD
DOI: 10.1142/S1088424611003768
Keywords
synthesis; brominated porphyrins; meso-tetraarylporphyrins; metalloporphyrins; electrochemical redox; cyclic voltammetry
Categories
Funding
- Department of Science and Technology (Government of India)
Ask authors/readers for more resources
A series of 2,3,12,13-tetrabromo-5,10,15,20-tetrakis(4'-substituted phenyl)porphyrins, H2T(4'-R Ph)PBr4 (R = OCH3, t-butyl, H and CO2CH3) and their metal (Co(II), Cu(II), and Zn(II)) complexes were synthesized and their electrochemical redox properties were explored. The plot of E-1/2 vs. the Hammett parameter (sigma(p)) of the substituents (R) follow a fairly linear relationship for the ring centered redox potentials.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
