Journal
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
Volume 14, Issue 2, Pages 142-149Publisher
WORLD SCI PUBL CO INC
DOI: 10.1142/S1088424610001854
Keywords
zinc phthalocyanine; transient methods; electrodeposition; ionic; nanocrystalline
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Funding
- German Ministry of Education [SUA 07/006]
- Research BMBF [SUA 07/006]
- South African National Research Foundation NRF [16 SV 3454]
- South African Department of Science and Technology (DST)
- DST/NRF South African Research Chair
- Rhodes University and Justus-Liebig-University Giessen
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Hybrid thin films of crystalline zinc oxide (ZnO) modified by different octacarboxymetallophthalocyanines (MOCPc) were prepared by the readsorption method. Homogeneously blue or green thin films were formed. The photoelectrochemical characteristics of the electrodes were studied by time-resolved photocurrent measurements. Zinc(II) 2,3,9,10,16,17,23,24-octacarboxyphthalocyanine (ZnOCPc) showed considerably large quantum efficiency in sensitization of ZnO, one of the highest quantum efficiencies obtained so far with phthalocyanine-type sensitizers on nanocrystalline ZnO films.
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