Journal
JOURNAL OF PORPHYRINS AND PHTHALOCYANINES
Volume 14, Issue 8, Pages 732-740Publisher
WORLD SCI PUBL CO INC
DOI: 10.1142/S1088424610002501
Keywords
ruthenium; homogenous catalysis; C-H amination
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Funding
- MiUR [2007HMTJWP_004]
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Benzylic amines are synthesized in yield up to 90% by the Ru(TPP)CO-catalyzed amination of both exocyclic and endocyclic benzylic C-H bonds. The choice of arylazides as nitrogen sources confers to the methodology a good sustainability due to the formation of molecular nitrogen as the only stoichiometric by-product. A preliminary mechanistic investigation evidenced a critical role of the hydrocarbon concentration to drive the chemoselectivity of the reaction.
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