Journal
JOURNAL OF POROUS MATERIALS
Volume 21, Issue 6, Pages 889-902Publisher
SPRINGER
DOI: 10.1007/s10934-014-9840-5
Keywords
Zeolitic imidazolate framework (ZIF); Substituted imidazole material (SIM-1); Microwave synthesis; Linker exchange
Funding
- Robert A. Welch Foundation [AT1153]
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Zeolitic imidazolate frameworks (ZIFs) are attractive materials for liquid and gas separations. They are chemically and thermally stable and their pores sizes/pore windows can be modified for enhanced performance. Substituted imidazolate material-1 (SIM-1) is a ZIF that crystallizes in the SOD and RHO topologies. Herein, we report a variety of new syntheses for SIM-1 in the SOD and RHO topologies using solvothermal in situ and ex situ reaction methods including microwave synthesis and linker exchange that result in nanoparticles with a narrow size distribution.
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