4.6 Article

Mechanical Properties of Microcrystalline Cellulose (MCC) Filled Engineering Thermoplastic Composites

Journal

JOURNAL OF POLYMERS AND THE ENVIRONMENT
Volume 22, Issue 3, Pages 365-372

Publisher

SPRINGER
DOI: 10.1007/s10924-014-0676-5

Keywords

Microcrystalline cellulose (MCC); Nylon 6; Mechanical properties; Engineering thermoplastic composites; Density

Funding

  1. republic of Turkey, Ministry of National Education
  2. Maine Agricultural and Forest Experiment Station (MAFES) [ME09615-08MS]
  3. Wood Utilization Research Hatch

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In this study, engineering thermoplastic composites were prepared from microcrystalline cellulose (MCC)-filled nylon 6. MCC were added to nylon 6 using melt mixing to produce compounded pellets. The MCC-filled nylon 6 composites with varying concentrations of MCC (from 2.5 to 30 wt%) were prepared by injection molding. The tensile and flexural properties of the nylon 6 composites were increased significantly with the addition of MCC. The maximum strength and modulus of elasticity for the nylon 6 composites were achieved at a MCC weight fraction of 20 %. The Izod impact strength of composites decreased with the incorporation of MCC without any surface treatments and coupling agent. This observation is quite expected for filled polymer systems and has been commonly observed. There was a strong correlation between density and tensile (r = 0.94) and flexural modulus of elasticity (r = 0.9). MCC filled composites manufactured by injection method had highly uniform density distribution through their thickness. The higher mechanical results with lower density demonstrate that MCC can be used as a sufficient reinforcing material for low cost, eco-friendly composites in the automotive industry especially for under-the-hood applications (engine covers, intake manifolds and radiator end tanks) as well as in other applications such as the building and construction industries, packaging, consumer products etc.

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