Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 52, Issue 18, Pages 2588-2595Publisher
WILEY
DOI: 10.1002/pola.27274
Keywords
organic-inorganic hybrid; POSS; refractive index; sulfur
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Funding
- Suzuki Foundation
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [25102521]
- Grants-in-Aid for Scientific Research [24550227, 24102010, 25102521, 25620161, 25620162, 25102548] Funding Source: KAKEN
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In this manuscript, we present the hybrid materials with sulfur as an inorganic element. Initially, the network polymers with the polysulfide-bridged polyhedral oligomeric silsesquioxane were synthesized and mixed with polystyrene and poly(methyl methacrylate). The resulting polymer blends showed higher thermal degradation temperatures than that of the polymer matrix similarly as typical hybrids. Next, it was found that the sulfur-bridging networks can increase refractive indices of the polymer matrices. Moreover, it was revealed that the loss of Abbe numbers was hardly observed by blending to conventional polymers. (C) 2014 Wiley Periodicals, Inc.
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