Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 52, Issue 9, Pages 1344-1352Publisher
WILEY
DOI: 10.1002/pola.27123
Keywords
biomaterials; bimetallic; catalysts; lactide; polymerization
Categories
Funding
- National Natural Science Foundation of China [21204082, 51173183, 21004061, 51203155, 51021003]
- Ministry of Science and Technology of China [2011AA02A202]
Ask authors/readers for more resources
A series of bimetallic aluminum Schiff-base complexes have been prepared and characterized. The complexes used as catalysts were applied in the lactide polymerization to test their activities and stereoselectivities. All polymerizations are living, as evidenced by the narrow polydispersities and the good fit between calculated and found number-average molecular weights of the isolated polymers. Isotactic enriched polylactide was obtained by using these complexes. Kinetic studies indicated that the polymerizations are both first-ordered with respect to lactide monomer and catalyst. (c) 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 1344-1352
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
