Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 51, Issue 10, Pages 2260-2270Publisher
WILEY
DOI: 10.1002/pola.26610
Keywords
biomaterials; crosslinking; Diels-Alder click; unclick polymerization; hyperbranched; nonlinear polycondensation; renewable resources; thermoreversible polymers
Categories
Funding
- FCT (Fundacao para a Ciencia e Tecnologia)
- POPH/FSE [SFRH/BD/44884/2008]
- Associate Laboratory CICECO [Pest-C/CTM/LA0011/2011]
- Fundação para a Ciência e a Tecnologia [SFRH/BD/44884/2008] Funding Source: FCT
Ask authors/readers for more resources
Novel trifunctional monomers based on renewable resources were prepared and subsequently polymerized via the Diels-Alder (DA) polycondensation between furan and maleimide complementary moieties. Three basic approaches were considered for these nonlinear DA polycondensations, namely the use of (i) a bisfuran monomer in combination with a trismaleimide (A2 + B3 system) and (ii) a trisfuran monomer in conjunction with a bismaleimide (A3 + B2 system) leading to branched or crosslinked materials, and (iii) the use of monomers incorporating both furan and maleimide end groups (A2B or AB2 systems), which lead to hyperbranched structures. The application of the retro-DA reaction to the ensuing polymers confirmed their thermoreversible character. (c) 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013, 51, 2260-2270
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available