Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 51, Issue 20, Pages 4459-4466Publisher
WILEY
DOI: 10.1002/pola.26864
Keywords
fluorescence; gel permeation chromatography (GPC); reversible addition fragmentation chain transfer (RAFT); stimuli-responsive amphiphilic copolymer
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Funding
- National Nature Science Foundation of China [21274100]
- Qing Lan Project
- Program of Innovative Research Team of Soochow University
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Project of International Cooperation of the Ministry of Science and Technology of China [2011DFA50530]
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A stimuli-responsive amphiphilic copolymer poly(NIPAM(m)-b-VBNBIn), including N-isopropylacrylamide (NIPAM) as a thermoresponsive unit and 1-(4-vinyl benzyl)-2-naphthyl-benzimidazole (VBNBI) as a sensitive fluorophore unit, was designed and synthesized by reversible addition-fragmentation chain transfer polymerization. The aqueous solutions of the copolymers exhibited reversible fluorescent response to pH and temperature. In addition, the copolymers showed aggregation-induced fluorescence enhancement in THF/water mixture. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2013, 51, 4459-4466
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