Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 51, Issue 1, Pages 94-100Publisher
WILEY
DOI: 10.1002/pola.26275
Keywords
conjugated polymers; dyes; pigments; structure-property relations; thin films
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Funding
- National Natural Science Foundation of China (NSFC) [21174084, 60976050]
- National Basic Research Program of China (973 Program) [2012CB932402]
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A new conjugated polymer PBDTT-ID based on N-alkylated isoindigo (ID) and bis(2,3-dialkylthienyl)-substituted benzo[1,2-b:4,5-b']dithiophene (BDTT) as repeating units was synthesized. It had an optical bandgap of 1.56 eV and a highest occupied molecular orbital (HOMO) energy level of -5.71 eV. The optical, electrochemical, and photovoltaic properties of new polymer were compared with previous reported polymer PBDT-ID, which was based on bis(alkoxy)-substituted benzo[1,2-b:4,5-b']dithiophene. The new polymer displayed lower HOMO energy level and better absorption properties than polymer PBDT-ID. The solar cells fabricated with PBDTT-ID/PC61BM (1:2, w/w) blends as active layers exhibited photoresponse in the range of 300-800 nm. A power conversion efficiency of 4.02% and an open circuit voltage (Voc) of 0.94 V were achieved in polymer solar cell device based on the new polymer. This was the highest Voc realized among the isoindigo-based polymers. The relatively high performances of new polymer in solar cell devices were interpreted in terms of material properties and morphologies of polymer/PCBM blends. (C) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013
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