Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 50, Issue 13, Pages 2641-2649Publisher
WILEY
DOI: 10.1002/pola.26038
Keywords
corannulene; fullerenes; host-guest systems; polymer synthesis; star polymers
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Funding
- Swiss National Science Foundation (SNSF), Ambizione [PZ00P2-126615]
- Swiss National Science Foundation (SNF) [PZ00P2_126615] Funding Source: Swiss National Science Foundation (SNF)
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We report the synthesis and properties of star polymers with a C-5-symmetric aromatic core. For this, corannulene-based penta-substituted polymerization initiators were synthesized. These initiators were then used to polymerize cyclic ester and styrenic monomers via ring opening polymerization and free radical polymerization methods, respectively. Preliminary results suggest that these novel polymers can interact with fullerene, C-60, and the degree of interaction can be tuned by the chemical nature of the solvent. (C) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 50: 26412649, 2012
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