Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 49, Issue 4, Pages 821-831Publisher
WILEY
DOI: 10.1002/pola.24491
Keywords
ADMET; functionalization of polymers; metathesis; polycondensation; step-growth polymerization
Categories
Funding
- National Science Foundation
- Army Research Office
- International Max Planck Research School
- Alexander von Humboldt Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1058079] Funding Source: National Science Foundation
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Although it is well known that Acyclic Diene METathesis (ADMET) describes an olefin metathesis polymerization mode that relies on double-bond substituent interchange of a diolefin, the story behind its discovery is not. The story is divulged here. Olefin metathesis has a rich history dating to the 1950s, but the one particular metathesis mode mentioned, ADMET, has more recent historical roots. ADMET polymerization is easy to do and highlighted here are the particular reac-tion details for success. Additionally, the most recent advances from the past 5 years are detailed, exemplifying this reaction's wide utility from fundamental structure-property studies to multiple advanced applications. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 821-831, 2011
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