Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 48, Issue 11, Pages 2462-2469Publisher
WILEY
DOI: 10.1002/pola.24017
Keywords
laser-induced polymers; photopolymerization; radical polymerization
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Triphenylphosphine (TPP) was used in free-radical UV-curable resins to reduce oxygen inhibition effect. The relative influence of concentration, monomer viscosity, light intensity and sample thickness on TPP efficiency was investigated by real time infrared spectroscopy. It is shown that TPP is an effective oxygen scavenger. The mechanism was investigated by means of Laser Flash Photolysis. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2462-2469, 2010
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