4.2 Article

Photopolymerization of Biocompatible Phosphorus-Containing Vinyl Esters and Vinyl Carbamates

Journal

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 48, Issue 13, Pages 2916-2924

Publisher

WILEY
DOI: 10.1002/pola.24072

Keywords

biocompatibility; photo-differential scanning calorimetry; photopolymerization; radical polymerization

Funding

  1. Austrian Science Fund FWF [P19769-N14]
  2. Austrian Science Fund (FWF) [P19769] Funding Source: Austrian Science Fund (FWF)

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Phosphorus-containing vinyl esters and vinyl carbamates were synthesized as new biocompatible and degradable photopolymers. Reactivity of the monomers with one, two, and three polymerizable double bonds was evaluated by photo-differential scanning calorimetry. With respect to their potential application in the biomedical field, studies on cytotoxicity, mechanical stability, and hydrolytic erosion behavior of the poly(vinyl alcohol)-based derivatives were performed. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2916-2924,2010

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