Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 49, Issue 3, Pages 814-819Publisher
WILEY
DOI: 10.1002/pola.24504
Keywords
block copolymer; click chemistry; cyclic polymers; heterogeneous catalysis; living free radical polymerization
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Funding
- National Heart, Lung and Blood Institute of the National Institutes of Health [HHSN268201000046C]
- National Science Foundation [DMR 05-20415, CHE 09-57492]
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A new method for the rapid and efficient coupling of homopolymers to yield diblock and triblock copolymers as well as cyclic polymers using the 3 + 2 pi Huisgen copper catalyzed cycloaddition reaction has been developed. This facile method utilizes commercially available Cu nanoparticles that are tolerant to O-2, easily removable and recyclable. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 814-819,2011
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