Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 47, Issue 19, Pages 4919-4926Publisher
WILEY
DOI: 10.1002/pola.23543
Keywords
catalytic activity; hollow spheres; PNIPAM-Ag nanocomposites; thermal sensitivity
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Funding
- Shanghai Chenguang Scholar Foundation [2007CG01]
- Research Fund for the Doctoral Program for New Teachers of Higher Education of China [200802461085]
- Shuguang Scholar-Tracking Foundation
- Natural Science Foundation of Shanghai [08ZR1400600]
- Foundation of Science and Technology of Shanghai [07DJ14004]
- Shanghai Leading Academic Discipline Project [B113]
- Shanghai Excellent Leader of Academic Discipline Project
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This article presents a strategy for the fabrication of hollow poly(N-isopropylacrylamide) (PNIPAM)-Ag nanocomposite spheres. In this approach, the thermosensitive PNIPAM hollow spheres were first synthesized via a one-pot self-removing process and then used as supporters for the coordination and in situ reduction of Ag+ ions. The results show that these hollow PNIPAM-Ag nanocomposite spheres still have typical thermal sensitivity, and importantly, these spheres have very good and controllable catalytic activity with five stages of variation versus temperature. (C) 2009 Wiley Periodicals, Inc. J Polyrn Sci Part A: Polym Chem 47: 4919-4926, 2009
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