4.2 Article

Fabrication and Properties of Hollow Poly(N-isopropylacrylamide)-Ag Nanocomposite Spheres

Journal

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 47, Issue 19, Pages 4919-4926

Publisher

WILEY
DOI: 10.1002/pola.23543

Keywords

catalytic activity; hollow spheres; PNIPAM-Ag nanocomposites; thermal sensitivity

Funding

  1. Shanghai Chenguang Scholar Foundation [2007CG01]
  2. Research Fund for the Doctoral Program for New Teachers of Higher Education of China [200802461085]
  3. Shuguang Scholar-Tracking Foundation
  4. Natural Science Foundation of Shanghai [08ZR1400600]
  5. Foundation of Science and Technology of Shanghai [07DJ14004]
  6. Shanghai Leading Academic Discipline Project [B113]
  7. Shanghai Excellent Leader of Academic Discipline Project

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This article presents a strategy for the fabrication of hollow poly(N-isopropylacrylamide) (PNIPAM)-Ag nanocomposite spheres. In this approach, the thermosensitive PNIPAM hollow spheres were first synthesized via a one-pot self-removing process and then used as supporters for the coordination and in situ reduction of Ag+ ions. The results show that these hollow PNIPAM-Ag nanocomposite spheres still have typical thermal sensitivity, and importantly, these spheres have very good and controllable catalytic activity with five stages of variation versus temperature. (C) 2009 Wiley Periodicals, Inc. J Polyrn Sci Part A: Polym Chem 47: 4919-4926, 2009

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