Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 47, Issue 16, Pages 4051-4063Publisher
WILEY
DOI: 10.1002/pola.23466
Keywords
acrylate; crosslinking; heteroatom-containing polymers; phosphorus-containing; renewable resources; triglyceride
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Funding
- CICYT (Comision Interministerial de Ciencia y Teenologia) [MAT2008-01,412]
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Phosphorus-containing triglycerides were prepared from a new route that involves the singlet oxygen photo-oxygenation of high oleic sunflower oil and further reduction of the resulting hydroperoxide derivatives to a mixture of secondary allylic alcohols. These allylic alcohols in presence of chlorodiphenylphosphine give allylic phosphinites capable to undergo a [2,3]-sigmatropic rearrangement leading to tertiary phosphine oxides directly linked to triglyceride in a one-pot two-step reaction. The obtained phosphorus-containing triglycerides with different hydroxyl content were activated to polymerization by acrylation and these acrylate triglycerides were radically crosslinked in presence of different amounts of pentaerythritol tetra-acrylate. The thermal, dynamic-mechanical, and flame retardancy properties of the final materials were evaluated. Thermal and thermo-oxidative degradation was studied by gas chromatography/mass spectrometry, P-31 HR-MAS NMR spectroscopy, and scanning electron microscopy. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 4051-4063, 2009
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