Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 47, Issue 23, Pages 6472-6495Publisher
WILEY
DOI: 10.1002/pola.23688
Keywords
fullerenes; host-guest systems; macrocycles; polyrotaxanes; self-assembly; star polymers
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Funding
- National Science Foundation [DMR-0097126, DMR-0704076, CHE043700]
- National Science Foundations [CHE-0722638]
- NIH Research Resource [P41RR0954]
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Multitopic dibenzylammonium, derivatives (4) of C-60 were prepared by Bingel reactions of C-60 with a malonate diester (2) containing two t-BOC protected dibenzylamine moieties, followed by deprotection and protonation. Self-assembly of model pseudorotaxanes 5 from the multidibenzylammonium C-60 derivatives with dibenzo-24-crown-8 was studied by H-1 NMR spectroscopy and mass spectrometry. Self-assembly of linear and star-shaped pseudorotaxanes 8 with up to 12 arms based on polystyrenes bearing terminal DB24C8 host units (7) and the guest functionalized C-60 salts was demonstrated by H-1 NMR spectroscopy and solution phase viscometry. These studies provide further evidence of the potential of supramacromolecular chemistry in construction of complex polymeric architectures. (C) 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47:6472-6495, 2009
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