Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 46, Issue 18, Pages 6165-6174Publisher
JOHN WILEY & SONS INC
DOI: 10.1002/pola.22927
Keywords
2-hydroxy-3-methacryloyloxypropoxybenzene; macroporous polymers; monomers; polymeric microspheres; suspension-emulsion copolymerization; swelling
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Synthesis and properties of the new difunctional methacrylate monomer 2-hydroxy-3-methacryloyloxypropoxybenzene are presented. This monomer was applied for the synthesis of porous microspheres. It was copolymerized with trimethylolpropane trimethacrylate in the presence of two pairs of pore-forming diluents dodecane and toluene, and n-decanol and toluene. Influence of diluents composition on their porous structures was studied. Thermal resistance and tendency to swell in different organic diluents for a chosen sample were also determined. (C) 2008 Wiley Periodicals, Inc.
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