Journal
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
Volume 46, Issue 9, Pages 3042-3047Publisher
JOHN WILEY & SONS INC
DOI: 10.1002/pola.22644
Keywords
photopolymerization; radiation; radical polymerization
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In this article, germanes are presented as new coinitiators for both radical and cationic photopolymerization processes. For the free radical polymerization process, the newly proposed structures are characterized by efficiencies similar or better than the reference amine. Germyl radicals are also found to be excellent initiators for free radical promoted cationic photopolymerization (FRPCP) of an epoxy resin. The associated reactivity is even better under air. (C) 2008 Wiley Periodicals, Inc.
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