Study on shearing resistance and the stability of O/W emulsion of the inclusive and hydrophobic association systems by activation energy methodology

The different polymer networks were constructed by two kinds of associations, one is host-guest inclusion between P(AM/A-beta-CD/NaA) and P(AM/BHAM/NaA), and the other is hydrophobic association of P(AM/BHAM/NaA). Under the high-speed shearing, the viscosity survival and recovery rate of different systems were investigated. The results show the inclusion complex (CD:BHAM = 2:1) has excellent shearing resistance performance, and it was also verified by dynamic light scattering (DLS). This is mainly because the strength of inclusive association is stronger than that of hydrophobic one. The conclusion was proved by time-temperature superposition as well. It shows that the activation energy E (a) of the inclusion complex (CD:BHAM = 2:1), which represents the strength of association, has a maximum value, while the activation energy E (b) of P(AM/BHAM/NaA) has also a maximum one because of the multiple associative sites of hydrophobic associations. The activation energy values of the inclusion complex (CD:BHAM = 1:1) are intermediate since there are two kinds of associations in this solution. This is exactly the reason that the complex (CD:BHAM = 1:1) has the best emulsifying property. Moreover, the conclusions related to emulsifying property have been verified by using a laser particle size analyzer and Turbiscan lab stability.