Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 29, Issue 4, Pages 209-215Publisher
WILEY
DOI: 10.1002/aoc.3270
Keywords
metal-organic framework; tin(IV) porphyrin; MIL-101(Cr); trimethylsilylation; tetrahydropyranylation
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Funding
- Research Council of the University of Isfahan
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The catalytic activity of 5,10,15,20-tetrakis(4-aminophenyl)porphyrinatotin(IV) trifluoromethanesulfonate, [Sn-IV(TNH2PP)(OTf)(2)], supported on chloromethylated MIL-101, was investigated in the trimethylsilylation of alcohols and phenols with hexamethyldisilazane (HMDS) and also their tetrahydropyranylation with 3,4-dihydro-2H-pyran. Excellent yields, mild reaction conditions, short reaction times and reusability of the catalyst without significant decrease in its initial activity are noteworthy advantages of this supported catalyst. Copyright (c) 2015 John Wiley & Sons, Ltd.
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