Journal
JOURNAL OF PHYSICS-CONDENSED MATTER
Volume 21, Issue 5, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/0953-8984/21/5/055005
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Funding
- Ministry of Education of the Czech Republic [LC06058, LA08022, MSM 0021620834]
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Using photoemission, we have studied the interaction of palladium with thin layers of stoichiometric ceria (Ce4+ character) and two mixed oxides, Ga-Ce-O and Sn-Ce-O, where cerium in the Ce3+ oxidation state is present. Palladium was found to partially reduce the CeO2 layer by introducing oxygen vacancies most probably in the vicinity of the growing Pd particles. In mixed oxide systems palladium very strongly interacts with both added metals-gallium and tin-leading to a breaking of metal-ceria bonds and the establishment of Pd-Ga(Sn) intermetallic compounds. As a consequence the ceria reoxidizes back to a Ce4+ oxidation state.
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