Journal
JOURNAL OF PHYSICS-CONDENSED MATTER
Volume 20, Issue 42, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/0953-8984/20/42/425216
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The Raman spectra of tetragonal TbPO4 (zircon-type I4(1)/amd structure, D-4h(19) space group) have been measured at ambient conditions and under variable pressure up to 15.5 GPa inside a diamond anvil cell (DAC). Assignment of the Raman active modes of the tetragonal phase has been carried out based on polarized measurements from a single oriented crystal of TbPO4 at ambient conditions. The abrupt Raman mode discontinuities and the appearance of numerous new Raman peaks at a pressure P-c approximate to 9.5 GPa have provided strong evidence for a first-order phase transition to a lower crystal symmetry, most likely monoclinic. The high-pressure structure appears to be more compact compared to the tetragonal one, and is retained upon bringing the crystal to ambient pressure.
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