Journal
JOURNAL OF PHYSICS D-APPLIED PHYSICS
Volume 46, Issue 41, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/0022-3727/46/41/415303
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Funding
- Council of Scientific and Industrial Research, Govt. of India, New Delhi
- DST (New Delhi) Nano-mission
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Double perovskite Y2FeCrO6 nanoparticles of diameter 40-60 nm have been prepared by a molten salt synthesis procedure. These exhibit ferromagnetic and relaxor-type ferroelectric transition. The presence of both Fe2+ and Cr2+ species is confirmed by XPS analysis. The magnetic properties have been explained on the basis of superexchange interaction between Fe2+/Fe3+ and Cr2+/Cr3+ and also Kanamori-Goodenough coupling between Fe3+/Cr3+ species. The relaxor-type behaviour is ascribed to dielectric loss arising due to small polaron hopping conduction between Fe2+/Fe3+ and Cr2+/Cr3+ pairs, respectively. A large magnetodielectric coefficient (similar to 25%) at room temperature is caused by a similar to 30% negative magnetoresistance for a magnetic field of 1.7 T. This has been explained by a model in which spin-polarized electrons hopping through the antiphase boundary contribute higher electrical conductivity to the system when a magnetic field is applied to it.
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