Journal
JOURNAL OF PHYSICS D-APPLIED PHYSICS
Volume 43, Issue 45, Pages -Publisher
IOP PUBLISHING LTD
DOI: 10.1088/0022-3727/43/45/455402
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Funding
- National Natural Science Foundation of China [50525204, 50832001]
- MOE [200801830025]
- Programme for Changjiang Scholars and Innovative Research Team in University
- Jilin University, China
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Graphene of 1-5 layers was synthesized on a polycrystalline Co film by radio-frequency plasma-enhanced chemical vapour deposition at a relatively low temperature of 800 degrees C for only 40 s in a mixture of gases of CH4/H-2/Ar (1/5/20, with a total gas flow rate of 78 sccm). The obtained graphene is of high quality as revealed by Raman spectroscopy and x-ray photoelectron spectroscopy. It exhibits a high optical transmittance of more than 70% in the wavelength range 500-1200 nm, and a sheet resistivity of 2661 Omega/sq. A possible formation mechanism is proposed. The significant influence of octahedral and tetrahedral lattice interstitial sites in the Co crystallites on the formation of graphene is discussed.
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