4.8 Article

Corrections to Thomas-Fermi Densities at Turning Points and Beyond

Journal

PHYSICAL REVIEW LETTERS
Volume 114, Issue 5, Pages -

Publisher

AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.114.050401

Keywords

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Funding

  1. NSF [CHE-1112442]
  2. Direct For Mathematical & Physical Scien
  3. Division Of Chemistry [1112442] Funding Source: National Science Foundation

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Uniform semiclassical approximations for the number and kinetic-energy densities are derived for many noninteracting fermions in one-dimensional potentials with two turning points. The resulting simple, closed-form expressions contain the leading corrections to Thomas-Fermi theory, involve neither sums nor derivatives, are spatially uniform approximations, and are exceedingly accurate.

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