Journal
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
Volume 73, Issue 2, Pages 193-197Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jpcs.2011.11.003
Keywords
Organometallic compounds; X-ray diffraction; Magnetic properties; Crystal structure
Funding
- British Council/PHC ALLIANCE
- EPSRC
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Variable temperature single crystal X-ray diffraction and SQUID magnetometry experiments have revealed a gradual spin transition in [Fe-II(L)](ClO4)(2) (where L=1,4,7-tris(2-aminophenyl)-1,4,7-triazacyclononane), centred around room temperature. The gradual nature of the spin transition has been attributed to the lack of significant intermolecular interactions between iron centres and the propensity of the counter ions to accommodate the internal strain in the crystal caused by spin crossover. (C) 2011 Elsevier Ltd. All rights reserved.
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