Activity-Induced Phase Separation and Self-Assembly in Mixtures of Active and Passive Particles

We investigate the phase behavior and kinetics of a monodisperse mixture of active (i.e., self-propelled) and passive isometric Brownian particles through Brownian dynamics simulations and theory. As in a purely active system, motility of the active component triggers phase separation into a dense and a dilute phase; in the dense phase, we further find active-passive segregation, with rafts of passive particles in a sea of active particles. We find that phase separation from an initially disordered mixture can occur with as little as 15% of the particles being active. Finally, we show that a system prepared in a suitable fully segregated initial state reproducibly self-assembles an active corona, which triggers crystallization of the passive core by initiating a compression wave. Our findings are relevant to the experimental pursuit of directed self-assembly using active particles.