Journal
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
Volume 26, Issue 7, Pages 608-610Publisher
WILEY-BLACKWELL
DOI: 10.1002/poc.3129
Keywords
aromaticity; azaquinone methide; controlled release; solvent effects
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Funding
- American Chemical Society [51618-DNI7]
- Arnold and Mabel Beckman Foundation
- Camille and Henry Dreyfus Foundation
- Alfred P. Sloan Research Fellows Program
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Herein we use small molecule models of stimuli-induced degradable/depolymerizable polymers to demonstrate that less aromatic releasing units provide faster rates of azaquinone methide-mediated release of benzylic phenols (a surrogate for a group released in a polymer) than highly aromatic releasing units. Copyright (c) 2013 John Wiley & Sons, Ltd.
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