☆ 4.2 Article Proceedings Paper

Recent excursions to the borderlands between the realms of concerted and stepwise: carbocation cascades in natural products biosynthesis

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY (2008)

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Journal

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
Volume 21, Issue 7-8, Pages 561-570

Publisher

JOHN WILEY & SONS LTD
DOI: 10.1002/poc.1320

Keywords

carbocation; concerted; synchronicity; terpene

Categories

Chemistry, Organic Chemistry, Physical

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Recent theoretical studies on concerted carbocation rearrangements that involve multiple asynchronous chemical events are described. The relevance of such rearrangements to natural products biosynthesis is highlighted. Copyright (c) 2008 John Wiley & Sons, Ltd.

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