Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 5, Issue 9, Pages 1591-1595Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jz500600w
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- Italian MIUR (PRIN) [2010ERFKXL_001]
- University of Bologna (RFO)
- MICINN for a Ramon y Cajal contract
- Spanish Ministry of Science and Innovation [CTQ2011-22923]
- Basque Government (Consolidated Groups) [IT520-10]
- UPV/EHU [UFI11/23]
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The pulsed jet Fourier transform microwave spectrum of the 1:1 complex between CF3Cl and CH3F shows that the two moieties are linked by a Cl center dot center dot center dot F halogen bond (R-Cl center dot center dot center dot F = 2.995 angstrom). The two symmetric tops CF3 and CH3 undergo free or almost free internal rotations, which alter the rigid value of the rotational constant A by almost 1 order of magnitude.
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