Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 4, Issue 3, Pages 486-490Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jz302135h
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Funding
- Ministerio de Ciencia e Innovacion (MICINN) [CTQ2006-05981/BQU, CTQ2010-19008, CSD2009-00038]
- Junta de Castilla y Leon [VA070A08]
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The rotational spectrum of neutral dopamine has been investigated for the first time using a combination of Fourier transform microwave spectroscopy with laser ablation. The parameters extracted from the analysis of the spectrum unequivocally identify the existence of seven conformers of dopamine. N-14 nuclear quadrupole coupling interactions have been used to determine the orientation of the amino group probing the existence of stabilizing N-H center dot center dot center dot pi interactions for all observed conformers.
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