4.8 Article

Highly Emissive H-Aggregates or Aggregation-Induced Emission Quenching? The Photophysics of All-Trans para-Distyrylbenzene

Journal

JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 4, Issue 16, Pages 2686-2697

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jz400985t

Keywords

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Funding

  1. Spanish Ministerio de Economia y Competitividad (MINECO) [CTQ2011-27317]
  2. Comunidad de Madrid [S2009/MAT-1726, S2009/PPQ1533]
  3. Ramon y Cajal fellowships of the MINECO
  4. EC via the COFUND program AMAROUT

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The present Perspective critically re-examines the photophysics of para-distyrylbenzene (DSB) as a prototype of herringbone-arranged H-aggregates to resolve the apparent contradiction of the frequently reported aggregation-induced emission quenching in H-aggregates on one side and highly emissive DSB crystals on the other and discusses the signatures and fate of excitons in single- and polycrystalline samples, including size and polarization effects.

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