Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 3, Issue 24, Pages 3781-3785Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jz301732n
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Funding
- Research Center Program of IBS (Institute for Basic Science) in Korea
- National Research Foundation of Korea (NRF)
- Korea Government (MEST) [2012-005624]
- MKE (The Ministry of Knowledge Economy), Korea, under the ITRC [NIPA-2012-H0301-12-1009]
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In the present work, we focused on geometrical (single- or double-tipped) and compositional (Pt or Au) variations of active metal components in a well-defined CdSe nanorod system. These colloidal nanostructures were employed for photocatalytic hydrogen generation from water under the identical reaction conditions with visible light irradiation. The catalysts exhibited significant dependency of the catalytic activity, specifically on the catalyst geometry and the choice of the metal tips, determined by the energetic consideration of electron transfer to the metal tips and hole transfer to the sacrificial reagents on the CdSe nanorods.
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