Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 3, Issue 10, Pages 1242-1247Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jz300430s
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- Oak Ridge National Laboratory
- Division of Chemical Sciences, Geosciences and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy
- Office of the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies of the U.S. Department of Energy
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In this work, we show that the use of a high boiling point ether solvent (tetraglyme) promotes the formation of Li2O2 in a lithium-air cell. However, another major constituent in the discharge product of a Li-air cell contains halides from the lithium salts and C-O from the tetraglyme used as the solvent. This information is critical to the development of Li-air electrolytes, which are stable and promote the formation of the desired Li2O2 products.
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