Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 3, Issue 17, Pages 2493-2499Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jz300940c
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Funding
- Division of Chemical Sciences, Geosciences and Biosciences, Office of Basic Energy Sciences of the U.S. Department of Energy [DE-FC02-04ER15533]
- National Science Council in Taiwan
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Silver nanoclusters complexed with dihydrolipoic acid (DHLA) exhibit molecular-like excited-state properties with well-defined absorption and emission features. The 1.8 nm diameter Ag nanoparticles capped with Ag-8 clusters exhibit fluorescence maximum at 660 nm with a quantum yield of 0.07%. Although the excited state is relatively short-lived (tau 130 ps), it exhibits significant photochemical reactivity. By introducing MV2+ as a probe, we have succeeded in elucidating the interfacial electron transfer dynamics of Ag nanoclusters. The formation of MV+center dot as the electron-transfer product with a rate constant of 2.74 x 10(10) s(-1) confirms the ability of these metal clusters to participate in the photocatalytic reduction process. Basic understanding of excited-state processes in fluorescent metal clusters paves the way toward the development of biological probes, sensors, and catalysts in energy conversion devices.
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