Journal
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 3, Issue 7, Pages 873-878Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jz201559g
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Funding
- National Science Foundation [CBET-1033346]
- National Science Foundation Nanoscale Science and Engineering Center at the University of Wisconsin - Madison [DMR-0832760]
- 3M Non-Tenured Faculty
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [832760] Funding Source: National Science Foundation
- Directorate For Engineering
- Div Of Chem, Bioeng, Env, & Transp Sys [1033346] Funding Source: National Science Foundation
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Charge and energy transport in organic semiconductors is highly anisotropic and dependent on crystalline ordering. Here, we demonstrate a novel approach for ordering crystalline organic semiconductors, with orientations optimized for optoelectronics applications, by using a single monolayer of graphene as a molecular template. We show, in particular, that large-area graphene can be integrated on metals and oxides to modify their surface energies and used to template copper phthalocyanine (CuPc), a prototypical organic semiconductor. On unmodified substrates, thermally evaporated films of CuPc are small-grained, and the molecules are in the standing-up (100) orientation. On graphene modified substrates, CuPc is templated in favorable lying-down (11 (2) over bar) and (01 (2) over bar) orientations with drastically larger crystal sizes. This results in an 86% increase in the absorption coefficient at 700 nm and should furthermore result in enhanced energy and charge transport. The use of highly conductive and transparent (>95%) graphene membranes as templates is expected to be a foundation for developing future planar and nanostructured organic light-emitting diodes and organic photovoltaics with improved performance.
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