4.8 Article

Utilization of Direct and Diffuse Sunlight in a Dye-Sensitized Solar Cell - Silicon Photovoltaic Hybrid Concentrator System

Journal

JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 2, Issue 6, Pages 581-585

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jz200112m

Keywords

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Funding

  1. U.S. Department of Energy, Office of Basic Energy Sciences [DE-FG02-05ER15756, DE-FG02-07ER15911]
  2. EU [212792]
  3. U.S. Department of Energy (DOE) [DE-FG02-07ER15911] Funding Source: U.S. Department of Energy (DOE)

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The concept of a tandem hybrid concentrator solar module was demonstrated from a dye-sensitized TiO2 solar cell (DSSCs) and a silicon p-n junction solar cell. The test system employed DSSC and Si cells with indoor AM1.5G efficiencies of 9.1 and 18.1%, respectively. Two different optical filters were used to selectively reflect and concentrate near-infrared light from the DSSC onto the Si cell. On the basis of outdoor testing in a 2 x concentrator reflector arrangement, the tandem system generated 93 and 96% of the output power of directly illuminated Si cells under altostratus/cirrostratus and clear sky irradiances, respectively, despite a DSSC-to-Si active area ratio of only 0.92. Similar performance is expected at higher (5-10 x) concentration ratios. The hybrid arrangement of visible- and IR-absorbing solar cells addresses the problem of lower performance of conventional concentrators under diffuse irradiance conditions. These proof-of-concept results suggest that system level efficiencies approaching 20% should be achievable.

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