4.8 Article

Analysis of Recombination Losses in a Pentacene/C60 Organic Bilayer Solar Cell

Journal

JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 2, Issue 21, Pages 2759-2763

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jz201338d

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Funding

  1. EPSRC Supergen
  2. APEX programmes
  3. Engineering and Physical Sciences Research Council [EP/H040218/1, EP/H040218/2] Funding Source: researchfish
  4. EPSRC [EP/H040218/2, EP/H040218/1] Funding Source: UKRI

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Transient photovoltage and charge extraction analyses are used to quantify the rate of nongeminate recombination loss within a pentacene/C-60 bilayer solar cell across the power-generating quadrant of the device. Employing these data, a simple model of cell function, based on field-independent generation and a charge-dependent nongeminate loss current without the use of any adjustable fitting parameters, is shown to be in good agreement with the experimental current/voltage behavior of the device both in the dark and under illumination.

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