4.8 Article

Luminescent Photoinduced Electron Transfer (PET) Molecules for Sensing and Logic Operations

Journal

JOURNAL OF PHYSICAL CHEMISTRY LETTERS
Volume 2, Issue 22, Pages 2865-2871

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jz201311p

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Chemical species can serve as inputs to supramolecular devices so that a luminescence output is created in a conditional manner. Conditionality is built into these devices by employing the classical photochemical process of photoinduced electron transfer (PET) to compete with luminescence emission. The response of these devices in the analogue regime leads to sensors that can operate in nanometric, micrometric, and millimetric spaces. Some of these devices serve in membrane science, cell physiology, and medical diagnostics. The response in the digital regime leads to Boolean logic gates. Some of these find application in improving aspects of medical diagnostics and in identifying small objects in large populations.

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