4.6 Article

Achieving High Dehydrogenation Kinetics and Reversibility of LiBH4 by Adding Nanoporous h-BN to Destabilize LiH

Journal

JOURNAL OF PHYSICAL CHEMISTRY C
Volume 122, Issue 41, Pages 23336-23344

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.8b07086

Keywords

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Funding

  1. Foundation for Innovative Research Groups of the National Natural Science Foundation of China [51621001]
  2. National Natural Science Foundation of China [U1601212, 51431001]
  3. Natural Science Foundation of Guangdong Province of China [2016A030312011]
  4. Guangdong Province Universities and Colleges Pearl River Scholar Funded Scheme (2014)

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Lithium borohydride (LiBH4) is a potential high-capacity hydrogen storage material but is limited by its high thermal stability and poor reversibility. Nanostructured hexagonal boron nitrides (h-BNs) with thin-layer (TL-BN) and nanoporous (NP-BN) structures have been prepared by treating h-BN in a hydrolysis process of LiBH4 and then mixing with LiBH4 by ball-milling to investigate their catalyzing effect on dehydrogenation and rehydrogenation. Nanostructured h-BN, in particular NP-BN, with an average pore size of 40 nm, significantly promotes the dehydrogenation kinetics, dehydrogenation capacity, and reversibility of LiBH4. For a LiBH4 + NP-BN (mole ratio 1:0.3) composite, the dehydrogenation capacity reaches 13.9 wt % for LiBH4 at 400 degrees C, which is very close to its theoretical one. The cycling capacity could remain stable at, similar to 7.6 wt % with rapid kinetics after de/rehydrogenation cycles under 10 MPa of hydrogen at 400 degrees C. The improved de/hydrogenation performance of LiBH4 depends on the nanoconfinement structure of LiBH4 in NP-BN. After dehydrogenation, a lithium-intercalated h-BN(LixBN) nanocrystal was formed by the reaction of h-BN and LiH. This LixBN nanocrystal confined the dehydrogenation products of the amorphous structure during dehydrogenation. Thus, this nanocrystal-confine-amorphous structure destabilizing LiH and benefiting the rehydrogenation and reversible capacity of the composite.

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