Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 118, Issue 28, Pages 15404-15411Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jp5040739
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Funding
- Ministry of Education and Science of the Russian Federation
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The microcrystals of monoclinic europium molybdate, alpha-Eu-2(MoO4)(3), have been fabricated by solid-state synthesis at T = 753-1273 K for 300 h. The crystal structure of alpha-Eu-2(MoO4)(3) has been refined by the Rietveld method and was found to belong to the space group C2/c with unit cell parameters a = 7.5576(1), b = 11.4709(2), c = 11.5158(2) angstrom, and beta = 109.278(1)degrees (R-B = 3.39%). About 40 narrow Raman lines have been observed in the Raman spectrum of the alpha-Eu-2(MoO4)(3) powder sample. The luminescence spectra of alpha-Eu-2(MoO4)(3) under excitation at 355 and 457.9 nm reveal domination of induced electric dipole transition D-5(0) -> F-7(2) and the presence of ultranarrow lines at D-5(0) -> F-7(0) and D-5(1) -> F-7(0) transitions.
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